Copper oxychloride

    WARNING: This product is for research use only, not for human or veterinary use.

MedKoo CAT#: 558135

CAS#: 1332-40-7

Description: Copper oxychloride is a fungicide.

Chemical Structure

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Copper oxychloride
CAS# 1332-40-7
Instruction

Theoretical Analysis

MedKoo Cat#: 558135
Name: Copper oxychloride
CAS#: 1332-40-7
Chemical Formula: Cl2Cu2H3O3-
Exact Mass: 246.81
Molecular Weight: 249.010
Elemental Analysis: Cl, 28.47; Cu, 51.04; H, 1.21; O, 19.27

Price and Availability

This product is not in stock, which may be available by custom synthesis. For cost-effective reason, minimum order is 1g (price is usually high, lead time is 2~3 months, depending on the technical challenge). Quote less than 1g will not be provided. To request quote, please email to sales @medkoo.com or click below button.
Note: Price will be listed if it is available in the future.

Request quote for custom synthesis

Synonym: Agrizan; Areecop; Basic copper chloride; Blitox; Blitox 50;

IUPAC/Chemical Name: dicopper(II) dichloride trihydroxide

InChi Key: CPOSXJRGXIJOHG-UHFFFAOYSA-I

InChi Code: InChI=1S/2ClH.2Cu.3H2O/h2*1H;;;3*1H2/q;;2*+2;;;/p-5

SMILES Code: [OH-].[Cu+2].[Cl-].[OH-].[OH-].[Cu+2].[Cl-]

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >2 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

More Info:

Biological target:
In vitro activity:
In vivo activity:

Preparing Stock Solutions

The following data is based on the product molecular weight 249.01 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
Formulation protocol:
In vitro protocol:
In vivo protocol:

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1: Ferreira LC, Scavroni J, da Silva JR, Cataneo AC, Martins D, Boaro CS. Copper oxychloride fungicide and its effect on growth and oxidative stress of potato plants. Pestic Biochem Physiol. 2014 Jun;112:63-9. doi: 10.1016/j.pestbp.2014.04.010. Epub 2014 May 8. PubMed PMID: 24974119.

2: Bayram S, Genc A, Buyukleyla M, Rencuzogullari E. Genotoxicity and cytotoxicity of copper oxychloride in cultured human lymphocytes using cytogenetic and molecular tests. Cytotechnology. 2016 Oct;68(5):2027-36. doi: 10.1007/s10616-016-9943-8. Epub 2016 Jan 11. PubMed PMID: 26754841; PubMed Central PMCID: PMC5023576.

3: Paradelo M, Pérez-Rodríguez P, Arias-Estévez M, López-Periago JE. Effect of particle size on copper oxychloride transport through saturated sand columns. J Agric Food Chem. 2010 Jun 9;58(11):6870-5. doi: 10.1021/jf100367b. PubMed PMID: 20465213.

4: Paradelo M, Letzner A, Arias-Estévez M, Garrido-Rodríguez B, López-Periago JE. Influence of soluble copper on the electrokinetic properties and transport of copper oxychloride-based fungicide particles. J Contam Hydrol. 2011 Sep 25;126(1-2):37-44. doi: 10.1016/j.jconhyd.2011.06.004. Epub 2011 Jul 2. PubMed PMID: 21783270.

5: Helling B, Reinecke SA, Reinecke AJ. Effects of the fungicide copper oxychloride on the growth and reproduction of Eisenia fetida (Oligochaeta). Ecotoxicol Environ Saf. 2000 May;46(1):108-16. PubMed PMID: 10806001.

6: Garlich N, Da Cruz C, Da Silva AF, Carraschi SP, Malaspina IC, Pitelli RA, Bianco S. Diquat associated with copper sources for algae control: Efficacy and ecotoxicology. J Environ Sci Health B. 2016;51(4):215-21. doi: 10.1080/03601234.2015.1120611. Epub 2016 Jan 14. PubMed PMID: 26766580.

7: Beltran-Garcia MJ, Espinosa A, Herrera N, Perez-Zapata AJ, Beltran-Garcia C, Ogura T. Formation of copper oxychloride and reactive oxygen species as causes of uterine injury during copper oxidation of Cu-IUD. Contraception. 2000 Feb;61(2):99-103. PubMed PMID: 10802274.

8: Pose-Juan E, Paradelo-Pérez M, Rial-Otero R, Simal-Gándara J, López-Periago JE. Detachment of sprayed colloidal copper oxychloride-metalaxyl fungicides by a shallow water flow. Pest Manag Sci. 2009 Jun;65(6):615-23. doi: 10.1002/ps.1711. PubMed PMID: 19165728.

9: Gharieb MM, Ali MI, el-Shoura AA. Transformation of copper oxychloride fungicide into copper oxalate by tolerant fungi and the effect of nitrogen source on tolerance. Biodegradation. 2004 Feb;15(1):49-57. PubMed PMID: 14971857.

10: Pose E, Rial-Otero R, Paradelo M, López-Periago JE. Influence of soil characteristics on copper sorption from a copper oxychloride fungicide. J Agric Food Chem. 2009 Apr 8;57(7):2843-8. doi: 10.1021/jf803275k. PubMed PMID: 19334759.

11: Pose-Juan E, Rial-Otero R, Paradelo M, Simal-Gándara J, Arias M, López-Periago JE. Behaviour of metalaxyl as copper oxychloride-metalaxyl commercial formulation vs. technical grade-metalaxyl in vineyards-devoted soils. J Hazard Mater. 2010 Feb 15;174(1-3):181-7. doi: 10.1016/j.jhazmat.2009.09.034. Epub 2009 Sep 15. PubMed PMID: 19796871.

12: Ewing HP, Pesti GM, Bakalli RI, Menten JF. Studies on the feeding of cupric sulfate pentahydrate, cupric citrate, and copper oxychloride to broiler chickens. Poult Sci. 1998 Mar;77(3):445-8. PubMed PMID: 9521458.

13: Snyman RG, Reinecke AJ, Reinecke SA. Quantitative changes in digestive gland cells and oocytes of Helix aspersa, as biomarkers of copper oxychloride exposure under field conditions. Bull Environ Contam Toxicol. 2009 Jul;83(1):19-22. doi: 10.1007/s00128-009-9721-9. Epub 2009 May 12. PubMed PMID: 19434358.

14: Snyman RG, Reinecke SA, Reinecke AJ. Hemocytic lysosome response in the snail Helix aspersa after exposure to the fungicide copper oxychloride. Arch Environ Contam Toxicol. 2000 Nov;39(4):480-5. PubMed PMID: 11031308.

15: Pérez-Rodríguez P, Paradelo M, Rodríguez-Salgado I, Fernández-Calviño D, López-Periago JE. Modeling the influence of raindrop size on the wash-off losses of copper-based fungicides sprayed on potato (Solanum tuberosum L.) leaves. J Environ Sci Health B. 2013;48(9):737-46. doi: 10.1080/03601234.2013.780551. PubMed PMID: 23688224.

16: Snyman RG, Reinecke AJ, Reinecke SA. Quantitative changes in the digestive gland cells of the snail Helix aspersa after exposure to the fungicide copper oxychloride. Ecotoxicol Environ Saf. 2005 Jan;60(1):47-52. PubMed PMID: 15482839.

17: Ottesen AR, Gorham S, Pettengill JB, Rideout S, Evans P, Brown E. The impact of systemic and copper pesticide applications on the phyllosphere microflora of tomatoes. J Sci Food Agric. 2015 Mar 30;95(5):1116-25. doi: 10.1002/jsfa.7010. Epub 2014 Dec 11. PubMed PMID: 25410588; PubMed Central PMCID: PMC4368374.

18: Martins F, Soares ME, Oliveira I, Pereira JA, de Lourdes Bastos M, Baptista P. Tolerance and bioaccumulation of copper by the entomopathogen Beauveria bassiana (Bals.-Criv.) Vuill. exposed to various copper-based fungicides. Bull Environ Contam Toxicol. 2012 Jul;89(1):53-60. doi: 10.1007/s00128-012-0628-5. Epub 2012 Apr 8. PubMed PMID: 22484327.

19: M P, J S, J C NM, M AE, Lopez-Periago JE. Transport of copper oxychloride-based fungicide particles in saturated quartz sand. Environ Sci Technol. 2009 Dec 1;43(23):8860-6. doi: 10.1021/es901650g. PubMed PMID: 19943658.

20: Hloch O, Charvát J. [Acute copper poisoning by suicidal attempt]. Vnitr Lek. 2012 Apr;58(4):325-8. Czech. PubMed PMID: 22559810.