Lankanolide

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MedKoo CAT#: 598302

CAS#: 66539-15-9

Description: Lankanolide is the aglycon of lankamycin.


Price and Availability

Size Price Shipping out time Quantity
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Pricing updated 2020-08-10. Prices are subject to change without notice.

Lankanolide is not in stock, may be available through custom synthesis. For cost-effective reason, minimum 1 gram order is requested. The product will be characterized by NMR, HPLC and MS analysis. Purity (HPLC) is usually >98%. CoA, QC data, MSDS will be provided when product is successfully made. The estimated lead time is 2-3 months. Please send email to sales@medkoo.com to inquire quote.


Chemical Structure

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Theoretical Analysis

MedKoo Cat#: 598302
Name: Lankanolide
CAS#: 66539-15-9
Chemical Formula: C25H46O9
Exact Mass: 490.3142
Molecular Weight: 490.63
Elemental Analysis: C, 61.20; H, 9.45; O, 29.35


Synonym: Lankanolide;

IUPAC/Chemical Name: (2R,3R,4R,5R,6R,7S,9S,10S,11R,12S,13R)-6,7,10,12-tetrahydroxy-2-((2S,3S)-3-hydroxybutan-2-yl)-3,5,7,9,11,13-hexamethyl-14-oxooxacyclotetradecan-4-yl acetate

InChi Key: CVKROIGZNTWOSR-OPJYFGNZSA-N

InChi Code: InChI=1S/C25H46O9/c1-11-10-25(9,32)23(30)16(6)22(33-18(8)27)15(5)21(12(2)17(7)26)34-24(31)14(4)20(29)13(3)19(11)28/h11-17,19-23,26,28-30,32H,10H2,1-9H3/t11-,12-,13+,14+,15-,16-,17-,19-,20-,21+,22-,23+,25-/m0/s1

SMILES Code: C[C@@H]([C@@H]([C@H]1OC([C@@H]([C@H]([C@@H]([C@H]([C@H](C[C@](O)([C@@H]([C@H]([C@H]([C@H]1C)OC(C)=O)C)O)C)C)O)C)O)C)=O)C)O


Technical Data

Appearance:
Solid powder

Purity:
>98% (or refer to the Certificate of Analysis)

Shipping Condition:
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition:
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility:
Soluble in DMSO

Shelf Life:
>3 years if stored properly

Drug Formulation:
This drug may be formulated in DMSO

Stock Solution Storage:
0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code:
2934.99.03.00


References

1: Kochetkov NK, Yashunsky DV, Sviridov AF, Ermolenko MS. Stereocontrolled synthesis of lankanolide from 1,6-anhydro-beta-D-glucopyranose (levoglucosan): 1, synthesis of the C-1/7 and C-8/15 segments. Carbohydr Res. 1990 Apr 25;200:209-25. PubMed PMID: 2379206.

2: Hamada T. [New development of photo-induced electron transfer reaction and total synthesis of natural product]. Yakugaku Zasshi. 2005 Jan;125(1):1-16. Review. Japanese. PubMed PMID: 15635278.