Triphenyl bismuth

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MedKoo CAT#: 591257

CAS#: 603-33-8

Description: Triphenyl bismuth is a biochemical.

Chemical Structure

Triphenyl bismuth
CAS# 603-33-8

Theoretical Analysis

MedKoo Cat#: 591257
Name: Triphenyl bismuth
CAS#: 603-33-8
Chemical Formula: C18H15Bi
Exact Mass: 440.0978
Molecular Weight: 440.3
Elemental Analysis: C, 49.10; H, 3.43; Bi, 47.46

Price and Availability

Size Price Availability Quantity
5.0g USD 450.0 2 Weeks
25.0g USD 950.0 2 Weeks
100.0g USD 1650.0 2 Weeks
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Synonym: Triphenyl bismuth; NSC 465; NSC-465; NSC465

IUPAC/Chemical Name: Bismuthine, triphenyl-


InChi Code: InChI=1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;

SMILES Code: [Bi](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >2 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

Preparing Stock Solutions

The following data is based on the product molecular weight 440.3 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL

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*When preparing stock solutions always use the batch-specific molecular weight of the product found on the vial label and SDS / CoA (available online).

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5: Goswami M, Ashley DC, Baik MH, Pohl NL. Mechanistic Studies of Bismuth(V)-Mediated Thioglycoside Activation Reveal Differential Reactivity of Anomers. J Org Chem. 2016 Jul 15;81(14):5949-62. doi: 10.1021/acs.joc.6b00860. Epub 2016 Jun 24. PubMed PMID: 27295299.

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8: Berger RJ, Rettenwander D, Spirk S, Wolf C, Patzschke M, Ertl M, Monkowius U, Mitzel NW. Relativistic effects in triphenylbismuth and their influence on molecular structure and spectroscopic properties. Phys Chem Chem Phys. 2012 Nov 28;14(44):15520-4. doi: 10.1039/c2cp43471g. Epub 2012 Oct 17. PubMed PMID: 23072773.

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10: Xu H, Abdulghani S, Behiri J, Sabokbar A. Osteolytic potential of triphenyl bismuth as an alternative contrast medium in acrylic bone cement. J Biomed Mater Res B Appl Biomater. 2005 Oct;75(1):64-73. PubMed PMID: 16015616.

11: Abdulghani SN, Nazhat SN, Behiri JC, Deb S. Effect of triphenyl bismuth on glass transition temperature and residual monomer content of acrylic bone cements. J Biomater Sci Polym Ed. 2003;14(11):1229-42. PubMed PMID: 14768910.

12: Thurston JH, Whitmire KH. Molecular precursors for ferroelectric materials: synthesis and characterization of Bi2M2(mu-O)(sal)4(Hsal)4(OEt)2 and BiM4(mu-O)4(sal)4(Hsal)3(O(i)Pr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta). Inorg Chem. 2003 Mar 24;42(6):2014-23. PubMed PMID: 12639136.

13: Arata T, Oyama Y, Tabaru K, Satoh M, Hayashi H, Ishida S, Okano Y. Cytotoxic effects of triphenylbismuth on rat thymocytes: comparisons with bismuth chloride and triphenyltin chloride. Environ Toxicol. 2002 Oct;17(5):472-7. PubMed PMID: 12242678.

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17: Mattie PA, Rawls HR, Cabasso I. Development of a radiopaque, autopolymerizing dental acrylic resin. J Prosthodont. 1994 Dec;3(4):213-8. PubMed PMID: 7866504.

18: Rawls HR, Marshall MV, Cardenas HL, Bhagat HR, Cabasso I. Cytotoxicity evaluation of a new radiopaque resin additive--triphenyl bismuth. Dent Mater. 1992 Jan;8(1):54-9. PubMed PMID: 1521685.